On another forum, someone said the E350/E450 steel rims have stamped into the steel, a max of 80 PSI.
On Tire America's website, The Nexen Roadian CT8 HL tire with a 3195 pound rating for $134.91 has a max tire pressure of 83 psi, just 3 pounds over the rating of the E450 steel wheel. I would think that is within the margin of safety.
Their other tire, General Grabber HD for $190.99 has a 90 psi max which is uncomfortable for me.
The third tire, Continental Vanco 4 Season for $226.99 has an 83 psi max. Max psi was not available but I found the psi number from Tire Rack's website. They sell the same tire for $237.53.
Tire Rack also sell Continental VanContact A/S for $240.69 with a 90 psi max.
There seems to be two basic groups of "Load 121" 3195 pound rated tires. Some have a max psi of 83, others have a max of 90. I suggest to limit yourself to ones with a max tire pressure of 83 PSI as not to exceed the steel wheel except by just 3 psi. But I am surely no expert on this subject. Think of me as "The Messenger" with an opinion.