Hello , I find it interesting that you are allowing wire gauge and a fuse to control the current flow for your lithium battery. Like you said
lithium batteries have a lower internal resistance and will draw current almost like a short. Here is my understanding on the alternator current charging circuit for my house battery on my 2017 2552. The relay under the hood below the coolant overflow container is what allows the house battery to be charged. The relay also is operated by the white switch on the dash so you can supplement the chassis battery with the house battery if the chassis battery needs a boost. My question to you is this an efficient/effective way of charging your new lithium ion batteries? No its not and here is why, you are relying on safeties for charging a fuse, wire diameter and BMS etc. Plus you are not controlling the current effectively to ensure your $$$$ batteries are being charge correctly. The original system was intended for like in kind batteries being charged from the alternator (lead acid).
Here is what my plans are, disable the relay when the engine is started to charge the house batteries but leave it so the white switch on the dash will still allow the relay to close if the chassis battery needs a boost. Then choose the DC to DC converter that best fits my needs 30amp, 40amp, 60amp etc. Wire it from the alternator to the DC to DC converter and then to the house battery using the proper AWG sized wire for the current flow. The DC to DC converters I believe use a trigger wire to start charging after the engine is started to prevent from draining down the chassis battery. Now I will be able to charge my battery faster, safer and with-in manufactures specs. Which should allow me to achieve maximum life cycles.
Solar charge controllers are a great way to charge lithium batteries as long as they have that charge profile for lithium batteries. If you are using a MPPT controller even better its almost 25% more efficient in lower light situations then PWM. This however is only one way to get your lithium batteries charged. Your converter is another, which you say is already capable of charging lithium batteries by the flipping of a switch to achieve the correct charging profile, why wouldn't you go the rest of the way and ensure that your alternator is doing the best for your lithium batteries?
Everyone is talking about Battle Born batteries as being the best choice. Don't get me wrong they are good batteries but I don't believe the best the market has to offer. I just had an opportunity to tour the Lithionics battery factory in Clearwater Fl, and I can say that they have surpassed build quality and BMS technology of the Battle Born batteries. Here is why, they are UL certified.... They are the first and only 12V lithium battery manufacturer to hold this certification. This means no matter what you do to there battery you will not have a runaway event (cascading cell failure). The batteries use prismatic cell design like a
newer Tesla most auto manufacturers except Tesla... This means fewer connection points unlike the round cell technology of Battle Born which is like a bicycle battery using a bunch of spot welds... The battery housing is made of aluminum and the BMS is mounted to the inside of the cover, using it as a heat sink a very effective way to remove heat associated with all BMS's. The battery comes with a heating blanket made into the case, so the battery will still operate at low temps. The battery is blue tooth capable, you can see every cells voltage, every charging event, discharge event, when the battery was born, serial number etc. Lithioncs has developed secondary alternator packages with Balmar and Waze specific for lithium batteries. The Waze alternator actually communicates with the BMS to achieve optimal charging on Lithionics. There battery also has a switch that can be used to turn off the battery for storage, and if you want the switch can be remote located by adding another switch by simply plugging into a port. These are just some of the basics I got from the tour. While I was there I found out that they just got a contract with Newmar to supply batteries, and they have had a contract with Winnebago and Coachman as well. This should give you some food for thought... There is a youtube video that compares Battle Born to Lithionics check it out. Here is the link
https://www.youtube.com/watch?v=Tt0joJc9HPo&t=6sVery Respectfully
Lance