As I said, I am certainly not an expert, or even close, on mold; but, I don't believe boiling water does anything but kill whatever is alive in the water. I don't believe it removes any "food for mold" in the water. Also, a half or more filled jug isn't the same environment as a closed 40+ gallon tank with a few cups of water left in it that is in an RV parked in one spot over the winter.
But I certainly could be wrong.